Timothy, your listening setup is remarkably similar to mine. I just don't have the wall issue with the surrounds, and the sub isn't behind anything. I have 5 identical bookshelf monitors, all within a few inches inches of being the same distance from my "listening throne" (I like that too), and at the same height (this last thing is important IMHO). If I sit back and relax on my throne the surrounds become more on axis to my ears, and the level increases slightly, which of course always sounds better because of that level increase, although I'm sure some of the difference I hear is due to the on/off axis response of the speakers. But most of the time that I listen seriously, I do not sit back. I sit forward on my throne. I find this does significantly change the perceived rear levels, and increases the perceived front levels as well. But if I set the system up based in the forward throne position and then recline, this produces a sound that I dislike because the rear sound center axis are falling in front of my ears and the front gets slightly lower in level. So I set it up assuming a reclined listening position.
When I explain to first time guests that there is a significant difference in the two listening postures, I always get funny looks, until they actually listen while sitting back and sitting forward. It is easy to detect.
Am I the only one who notices this?