That's what I've been doing using XLD (X Lossless Decoder).
Normally I tend to not trust anyone and like to test things myself...
But I don't have DSD converters (AD or DA) or a DSD format DAW app. I don't have any utility to convert PCM to DSD either right now either. (That people are converting DSD to PCM and not asking for the other way around should tell you something...)
So, I'm going by the brochure on this one!
If I had an allegedly lossless PCM to DSD conversion app, I'd convert one back and do a null test in a DSD format DAW. A perfect null from subtracting one file from the other is as black and white as it can get that they are 100% identical sets of ones and zeros.